Local garage bins Super Unleaded.

Local garage bins Super Unleaded.

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kambites

67,578 posts

221 months

Thursday 8th December 2016
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Riley Blue said:
kambites said:
I'm not sure I've ever seen anyone using the "super diesel" pumps. I don't even know what the difference is supposed to be; obviously it's not octane rating.
'Cetane' is the diesel buzz word roughly equivalent to 'octane' I believe.
"Cetane rating" is roughly equilevant to "octane rating" in that it measures at what pressure a fuel will spontaneously combust (in fact it's the inverse of it, a higher cetane rating means a fuel will ignite more easily under compression). Unlike with petrol and Octane, I don't think diesel actually contains the chemical called Cetane though?

Of course the difference is that with a spark ignition engine, you simply want the highest octane rating possible. With a compression ignition engine there is no "right" cetane rating; you just want whatever the engine is tuned for.

Edited by kambites on Thursday 8th December 19:57

PositronicRay

27,034 posts

183 months

Thursday 8th December 2016
quotequote all
kambites said:
Of course the difference is that with a spark ignition engine, you simply want the highest octane rating possible.

Edited by kambites on Thursday 8th December 19:57
Not sure I understand this?

amancalledrob

1,248 posts

134 months

Friday 9th December 2016
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PositronicRay said:
kambites said:
Of course the difference is that with a spark ignition engine, you simply want the highest octane rating possible.

Edited by kambites on Thursday 8th December 19:57
Not sure I understand this?
When the air/fuel mix is compressed in the cylinder it gets hotter. If it gets too hot it will auto-ignite before the spark plug fires - this is detonation, uncontrolled combustion of the mixture otherwise known as 'knock'. A higher octane rating reduces the tendency of the fuel to detonate under compression, so that the spark plug can ignite it at the right time for a controlled burn.


TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
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amancalledrob said:
PositronicRay said:
kambites said:
Of course the difference is that with a spark ignition engine, you simply want the highest octane rating possible.
Not sure I understand this?
When the air/fuel mix is compressed in the cylinder it gets hotter. If it gets too hot it will auto-ignite before the spark plug fires - this is detonation,
Which in a diesel, of course, is exactly how it runs (and, on older stuff with carbs, using too low octane fuel can also cause running on, as fuel's still available, and is being ignited without a spark. To combat that, carbs started to be fitted with shut-off solenoids on the fuel supply.)

But, as you say, in a petrol...

amancalledrob said:
uncontrolled combustion of the mixture otherwise known as 'knock'.
Which, if left unchecked, can cause serious damage to engine internals - burning holes in the piston crown, and other damage.

amancalledrob said:
A higher octane rating reduces the tendency of the fuel to detonate under compression, so that the spark plug can ignite it at the right time for a controlled burn.
Indeed. Counter-intuitively, higher octane fuel is harder to ignite.

But... so long as there's no pre-ignition, then higher octane fuel will make zero difference. And that's where some engines can take advantage - because they can see no pre-ignition is happening, so can change the map (with a range) until pre-ignition DOES occur, then bring it back a snidge - ensuring that the full advantage is taken from the fuel's resistance to ignition. So a given engine may well run just fine on 95, but can adjust for 97 or 98. Beyond there, though, there's no benefit to using 100 or more if you can find it.

Back in the day, two star leaded was 92 octane, three star was 95, four star was 98, and five star was 101. When unleaded first came out across Europe, in the 80s, there was regular (91), premium (95) and super (97-98) - regular never made it here, and has died out on the continent - so a lot of cars had to be retuned from 98 octane to 95, so they'd run on premium unleaded - that was easy back then, just changing the ignition timing.

AvGas is 100, but measured differently. The US have 87 (regular), 88-90 (mid) and 91-94 (premium), measured differently again.

kambites

67,578 posts

221 months

Friday 9th December 2016
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TooMany2cvs said:
But... so long as there's no pre-ignition, then higher octane fuel will make zero difference.
Indeed but there's no disadvantage in a higher octane rating, even then (assuming the higher octane rating isn't created at the expense of actual energy content). My point was that there is a clear goal for spark ignition fuel - you simply want as much knock resistance as you can get; there may be a point past which it's not particularly useful, but it's never a bad thing. There is no clear "best" Cetane rating for diesel fuel so there's no reason that "super" diesel would have a higher or lower Cetane rating than normal diesel.

If 200RON petrol was available at the same price as 95RON, manufacturers would be designing engines to make use of its (presumably running 30:1 compression ratios or something).

Edited by kambites on Friday 9th December 09:50

TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
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kambites said:
Indeed but there's no disadvantage in a higher octane rating
...cost aside.

kmabites said:
My point was that there is a clear goal for spark ignition fuel - you simply want as much knock resistance as practical.
Kinda. You need just enough knock resistance for the engine's setup.

kambites

67,578 posts

221 months

Friday 9th December 2016
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TooMany2cvs said:
Kinda. You need just enough knock resistance for the engine's setup.
Yes but you design the engine around the fuel that's readily available, not vice versa.

TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
quotequote all
kambites said:
TooMany2cvs said:
Kinda. You need just enough knock resistance for the engine's setup.
Yes but you design the engine around the fuel that's readily available, not vice versa.
I was coming more from the position that the engine's already designed, manufactured, and fitted into your car - and you're figuring out which pump to reach for.

PositronicRay

27,034 posts

183 months

Friday 9th December 2016
quotequote all
TooMany2cvs said:
kambites said:
Indeed but there's no disadvantage in a higher octane rating
...cost aside.

kmabites said:
My point was that there is a clear goal for spark ignition fuel - you simply want as much knock resistance as practical.
Kinda. You need just enough knock resistance for the engine's setup.
Which is what I thought.

liner33

10,691 posts

202 months

Friday 9th December 2016
quotequote all
kambites said:
Indeed but there's no disadvantage in a higher octane rating, even then (assuming the higher octane rating isn't created at the expense of actual energy content). My point was that there is a clear goal for spark ignition fuel - you simply want as much knock resistance as you can get; there may be a point past which it's not particularly useful, but it's never a bad thing. There is no clear "best" Cetane rating for diesel fuel so there's no reason that "super" diesel would have a higher or lower Cetane rating than normal diesel.

If 200RON petrol was available at the same price as 95RON, manufacturers would be designing engines to make use of its (presumably running 30:1 compression ratios or something).

Edited by kambites on Friday 9th December 09:50
Higher octane fuel burns slower so there is a trade off its not a case of more is better

kambites

67,578 posts

221 months

Friday 9th December 2016
quotequote all
liner33 said:
Higher octane fuel burns slower so there is a trade off its not a case of more is better
Sort of. Fuel with more Octane in it burns slower; fuel with a higher Octane rating does not necessarily. As with Cetane rating, Octane rating actually has nothing directly to do with the chemical it's named after; it just happens to be what is generally used to control it but there are other ways which don't have the same side-effects.

Flame-front speed and knock resistance are not fundamentally related to each other (although of course if the flash-point is higher than the combustion temperature the fuel wont manage to burn at all).

kambites

67,578 posts

221 months

Friday 9th December 2016
quotequote all
TooMany2cvs said:
I was coming more from the position that the engine's already designed, manufactured, and fitted into your car - and you're figuring out which pump to reach for.
Oh yes I agree entirely. I wasn't trying to claim there was any point in buying higher octane fuel for a car not designed to use it and indeed I run my Elise on 95RON. I was purely trying to understand what theoretical benefits "super" diesel could provide to instantaneous engine performance (as opposed to longevity).

I understand what super-unleaded is and why, in the right circumstances, it's better (and why in the wrong circumstances, it's not). I do not have the same understanding for super diesel.

Edited by kambites on Friday 9th December 10:21

TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
quotequote all
kambites said:
I do not have the same understanding for super diesel.
Likewise. Seems to be 100% marketing guff...

"OK, guys - a lot more people buy super unleaded than actually benefit from it - and we make a bigger margin. So let's try the same with diesel, where nobody benefits!"

Jim AK

4,029 posts

124 months

Friday 9th December 2016
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TooMany2cvs said:
Likewise. Seems to be 100% marketing guff...
. So let's try the same with diesel, where nobody benefits!"
No.

My car runs like a sack of ste on regular.

As I said in my earlier reply, so much so that when I couldn't get any & used regular I stopped the car after a couple of miles to check my receipt was for Diesel & I hadn't misfuelled.

TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
quotequote all
Jim AK said:
TooMany2cvs said:
Likewise. Seems to be 100% marketing guff...
. So let's try the same with diesel, where nobody benefits!"
No.

My car runs like a sack of ste on regular.

As I said in my earlier reply, so much so that when I couldn't get any & used regular I stopped the car after a couple of miles to check my receipt was for Diesel & I hadn't misfuelled.
Sounds more like you got some bad diesel in that fill.

So what car is this that won't run on ordinary diesel? And can you explain what and why this difference happens?

Jim AK

4,029 posts

124 months

Friday 9th December 2016
quotequote all
TooMany2cvs said:
Sounds more like you got some bad diesel in that fill.

So what car is this that won't run on ordinary diesel? And can you explain what and why this difference happens?
Just a Merc 220. Ive used it from new & now on 107k as a friend, who's current 220 is on over 300k, adviised it because his showed an improvement in economy over standard fuel & was smoother running.

amancalledrob

1,248 posts

134 months

Friday 9th December 2016
quotequote all
TooMany2cvs said:
Sounds more like you got some bad diesel in that fill.

So what car is this that won't run on ordinary diesel? And can you explain what and why this difference happens?
Bad diesel? How does that happen, then

TooMany2cvs

29,008 posts

126 months

Friday 9th December 2016
quotequote all
amancalledrob said:
TooMany2cvs said:
Sounds more like you got some bad diesel in that fill.

So what car is this that won't run on ordinary diesel? And can you explain what and why this difference happens?
Bad diesel? How does that happen, then
Contamination in the tank, usually.

kambites

67,578 posts

221 months

Friday 9th December 2016
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Interestingly, even Shell don't claim V-Power Diesel has any short-term effect on the engine, just that it keeps it cleaner which benefits long-term running.

daemon

35,829 posts

197 months

Friday 9th December 2016
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kambites said:
Interestingly, even Shell don't claim V-Power Diesel has any short-term effect on the engine, just that it keeps it cleaner which benefits long-term running.
Yes - presumably additives to aid cleaning etc.

Millers Diesel additive works out cheaper