Stainless steel corrosion.
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Discussion

Huntsman

Original Poster:

9,303 posts

279 months

Sunday 13th May 2012
quotequote all
There was some evidence inside the transom on Playtime that the exhaust outlet bolts had been leaking a little, I pulled the bolts in order to re-seal them. These have been in place for about 9 years.

The exhaust outlet has been bonded to the anode all the time, it seems that is not enough to prevent crevice corrsion.



Certainly stainless should not be considered a fit and forget material.

LimaDelta

8,397 posts

247 months

Sunday 13th May 2012
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Very true, but the same can be said for just about any material when exposed to salt/water/air/UV/heat/cold. Nothing lasts very long on a boat. Except sailors, but they tend to rot from the inside out.

bga

8,134 posts

280 months

Sunday 13th May 2012
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It's easy to forget that it's stain-less rather than stain-proof.

Huntsman

Original Poster:

9,303 posts

279 months

Sunday 13th May 2012
quotequote all
LimaDelta said:
Very true, but the same can be said for just about any material when exposed to salt/water/air/UV/heat/cold. Nothing lasts very long on a boat. Except sailors, but they tend to rot from the inside out.
Bronze.

Simpo Two

92,660 posts

294 months

Sunday 13th May 2012
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What about tungsten, titanium or some clever alloy?

LimaDelta

8,397 posts

247 months

Sunday 13th May 2012
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Why not gold? Ultimately it comes down to availability and cost. I'm pretty sure you won't find countersunk slotted M8x60 bolts in gold, tungsten, titanium or bronze at your local chandlers.

Huntsman

Original Poster:

9,303 posts

279 months

Sunday 13th May 2012
quotequote all
LimaDelta said:
Why not gold? Ultimately it comes down to availability and cost. I'm pretty sure you won't find countersunk slotted M8x60 bolts in gold, tungsten, titanium or bronze at your local chandlers.
I'm not so sure about tungsten, but certainly titanium is becoming more common, not seen it in the swindlery yet though.

hidetheelephants

35,694 posts

222 months

Sunday 13th May 2012
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Cunifer is pretty much the best no-cost-limit marine metal; there are(or were) fishing boats with cunifer hulls in some bit of south america. Eye-bleedingly expensive though.

Fasteners like that are exposed to exhaust products as well as seawater, even when bedded in sealant they probably need removing for inspection every 5 years or so; I've seen identically wasted SS bolts removed from the exhaust outlets on one of Playtime's siblings, and the exhaust outlet itself had crevice corrosion burrowing through the metal where the rubber hose was clamped on creating a low-oxygen environment.

rhinochopig

17,932 posts

227 months

Sunday 13th May 2012
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Stainless is also highly susceptible to chloride stress corrosion cracking if used in coolant pipework or sees a lot of heat and gets wet. Nasty stuff sea-water.

http://www.npl.co.uk/upload/pdf/stress.pdf

Edited by rhinochopig on Monday 14th May 09:16

Huntsman

Original Poster:

9,303 posts

279 months

Sunday 13th May 2012
quotequote all
hidetheelephants said:
Cunifer is pretty much the best no-cost-limit marine metal; there are(or were) fishing boats with cunifer hulls in some bit of south america. Eye-bleedingly expensive though.

Fasteners like that are exposed to exhaust products as well as seawater, even when bedded in sealant they probably need removing for inspection every 5 years or so; I've seen identically wasted SS bolts removed from the exhaust outlets on one of Playtime's siblings, and the exhaust outlet itself had crevice corrosion burrowing through the metal where the rubber hose was clamped on creating a low-oxygen environment.
That's interesting, I'd never heard of a cunifer hull, some of the Huntsman 31's had siamesed exhausts and I think the bifurcated (good word!) part is cunifer.

I can see cast bronze outlets for next year, bit of home casting maybe!!

Simpo Two

92,660 posts

294 months

Sunday 13th May 2012
quotequote all
LimaDelta said:
Why not gold? Ultimately it comes down to availability and cost. I'm pretty sure you won't find countersunk slotted M8x60 bolts in gold, tungsten, titanium or bronze at your local chandlers.
Gold is too soft. Unless you add one carat platinum of course biggrin

There must be some composite material where you could stamp out/mould the parts fairly cheaply then cure in an oven.

bucksmanuk

2,426 posts

199 months

Sunday 13th May 2012
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Inconel works well too in this kind of environment
again pant wettingly expensive
I've just had some inconel bolts delivered at work.
M8 x 35 - £14 each. They are going to sit at the bottom of a gas well though

hidetheelephants

35,694 posts

222 months

Monday 14th May 2012
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bucksmanuk said:
Inconel works well too in this kind of environment
again pant wettingly expensive
I've just had some inconel bolts delivered at work.
M8 x 35 - £14 each. They are going to sit at the bottom of a gas well though
Bit sour then?

Interesting write-up about the use of CuNi in ship hulls here.

Edited by hidetheelephants on Monday 14th May 00:24

mrloudly

2,815 posts

264 months

Monday 14th May 2012
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Crappy stainless. There's loads of different grades for stainless steel, some are a lot lot better than others in resisting corrosion.

http://en.wikipedia.org/wiki/Stainless_steel

MOTORVATOR

7,602 posts

276 months

Monday 14th May 2012
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Looking at the timescales you mention I would go with those not being A4 / 316.

It's all very nice going into a chandlers and picking up one of the prepacks off the shelf but not all prepacks are marine grade. They can also be any of three different tensile strength grades.

Best for something like that to order direct from a fastening company that know what they about.

m0ssy

920 posts

221 months

Monday 14th May 2012
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MOTORVATOR said:
Looking at the timescales you mention I would go with those not being A4 / 316.

It's all very nice going into a chandlers and picking up one of the prepacks off the shelf but not all prepacks are marine grade. They can also be any of three different tensile strength grades.

Best for something like that to order direct from a fastening company that know what they about.
yes When changing bits on mine always order from companies direct where I know its 316/ A4, and mine only sees salt water a few times a year!

Tango13

10,047 posts

205 months

Monday 14th May 2012
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doogz said:
Huntsman said:
I'm not so sure about tungsten, but certainly titanium is becoming more common, not seen it in the swindlery yet though.
IIRC Ti corrodes in the presence of Fe, i.e. steel.

Titanium is strange stuff. Lockheed had all sorts of problems when building the A12 and SR71 including spot welds failing due to the titanium reacting with the residue of chlorine from when the panels were washed prior to welding.

I've worked with it before and if the feeds and speeds are just right it's easy to get an excellent finish but if you're slightly off then it's a nightmare.

Cunnifer is even worse, it has, like Inconel a very high nickel content so it's tough as old boots and a bd to machine.

bucksmanuk

2,426 posts

199 months

Tuesday 15th May 2012
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[quote=hidetheelephants]
Bit sour then?
quote]
Thats the annoying bit - it isn't really!
Customer wants - customer gets....

hidetheelephants

35,694 posts

222 months

Tuesday 15th May 2012
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bucksmanuk said:
hidetheelephants said:
Bit sour then?
Thats the annoying bit - it isn't really!
Customer wants - customer gets - customer gets stupid tax applied to bill....
perhaps the above? hehe

mph1977

12,467 posts

197 months

Tuesday 15th May 2012
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as has been said not all stainless is born equal mixing 304 and 316 components can be quite destructive in some environments ...