Mine runs better on Shell Vpower than BP ultimate, but I could be imagining it... If you feel yours is running rough, get the throttle bodies tunned. Mine was rough in cold weather when I first got but the tune transformed it.
So far as I am aware the std TVR engine/ECU combo can't differentiate between the different octanes of fuel. That said I just avoid supermarket stuff and fill up with Shell or BP
Tam handbook say's "normal everday use - Premium unleaded 95 Ron Track use - Super unleaded 98 Ron" I use Shell 98, seems to suit the car and push on motoring just fine.